General description
(1,3-Dioxolan-2-ylmethyl)zinc bromide is an organozinc compound used as a reagent in Negishi cross-coupling reaction to prepare aryl or heteroaryl scaffolds via C-C bond formation.
Application
(1,3-Dioxolan-2-ylmethyl)zinc bromide can be used as a reagent in the allylic alkylation reactions in the presence of iridium catalyst.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Molecular Weight: 232.39. Empirical Formula: C
4H
7BrO
2Zn. form: liquid. Quality Level: 100. reaction suitability: reaction type: C-C Bond Formation. concentration: 0.6 . M in THF. density: 0.992 . g/mL . at 25 . °C. storage temp.: 2-8°C. SMILES string: Br[Zn]CC1OCCO1. InChI: 1S/C4H7O2.BrH.Zn/c1-4-5-2-3-6-4. . /h4H,1-3H2. 1H. /q. . +1/p-1. InChI key: LOJRLQRGBKTHDB-UHFFFAOYSA-M. Pictograms: GHS02,GHS07,GHS08. Signal Word: Danger. Hazard Statements: H225 - H302 - H315 - H319 - H335 - H336 - H351. Precautionary Statements: P202 - P210 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313. Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2. Supp Hazards: EUH019. Storage Class Code: 3 - Flammable liquids. WGK: WGK 3. Flash Point(F): -22.0 °F. Flash Point(C): -30 °C.