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(1R 2R)-(+)-1 2-DIPHENYLETHYLENEDIAMINE 97% (99% EE/GLC) (C15-1233-456)

Sigma Aldrich

Catalog No.
C15-1233-456
Manufacturer No.
364010-1G
Manufacturer Name
Sigma-Aldrich
Quantity
1
Unit of Measure
GR
Price: $219.86
List Price: $244.29

Application General applications: (1 R ,2 R )-(+)-1,2-Diphenylethylenediamine (DPEN) is one of the widely used chiral auxiliary and ligand in the synthesis of asymmetric catalysts such as BINAP/diamine-Ru complexes for the stereoselective

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Application

General applications:

  • (1R,2R)-(+)-1,2-Diphenylethylenediamine (DPEN) is one of the widely used chiral auxiliary and ligand in the synthesis of asymmetric catalysts such as BINAP/diamine-Ru complexes for the stereoselective hydrogenation of ketones.
  • It can be used in the preparation of monosulfonyl DPEN-salt to catalyze Michael addition of various ketones to maleimides.
  • DPEN-derived chiral triazolium salts can be used to catalyze enantioselective intramolecular Stetter reaction and oxodiene Diels-Alder reaction.
  • Zinc acetate complexes of DPEDA-derived ligands can also be used to catalyze hydrosilylation of imines.

UPC:
51314360
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
WeightUOM:
LB
MPN:
364010-1G

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