![(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate (c15-1291-598)](https://cdn11.bigcommerce.com/s-2u2oi3cvy8/images/stencil/1280x1280/products/915814/743743/cenmed-product-image-placeholder-1-__28875.1717468547.jpg?c=1 "(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate (c15-1291-598)")
General description
It is an N-mesityl-substituted chiral triazolium N-heterocyclic carbene (NHC) compound. It was developed as an organocatalyst by the Bode group, for the catalytic generation of reactive species including activated carboxylates, homoenolates, and enolates.
Application
(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate can be used as a catalyst:
- In the preparation of dihydropyridinones by reacting enals or α′-hydroxyenones with vinylogous amides via aza-Claisen annulations.
- In the oxidative coupling reactions of di(hetero)arylmethanes with enals to yield benzimidazole fused lactams.
- In the synthesis of organosilanes by reacting enals with β-silyl enones.
Legal Information
Sold in collaboration with BioBlocks, Inc.
- UPC:
- 51391904
- Condition:
- New
- Weight:
- 1.00 Ounces
- HazmatClass:
- No
- WeightUOM:
- LB
- MPN:
- 683973-250MG
![(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate (c15-1291-597)](https://cdn11.bigcommerce.com/s-2u2oi3cvy8/images/stencil/500x659/products/915813/743742/cenmed-product-image-placeholder-1-__22447.1717468546.jpg?c=1 "(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate (c15-1291-597)")
![(+)-(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium chloride monohydrate (c09-0721-383)](https://cdn11.bigcommerce.com/s-2u2oi3cvy8/images/stencil/500x659/products/760640/589025/A151505__43641.1717200642.png?c=1 "(+)-(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium chloride monohydrate (c09-0721-383)")
![(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate (c09-0736-841)](https://cdn11.bigcommerce.com/s-2u2oi3cvy8/images/stencil/500x659/products/776096/604026/sj_500_A466993__26936.1717208441.jpg?c=1 "(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate (c09-0736-841)")
![(+)-(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium chloride monohydrate (c09-0721-384)](https://cdn11.bigcommerce.com/s-2u2oi3cvy8/images/stencil/500x659/products/760641/589026/A151505__18268.1717200642.png?c=1 "(+)-(5ar,10bs)-5a,10b-dihydro-2-(2,4,6-trimethylphenyl)-4h,6h-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium chloride monohydrate (c09-0721-384)")
