(S)-(-)-1,1'-Bi(2-naphthol) (C15-1220-790)

Catalog No.: C15-1220-790
Manufacturer No.: 246956-25G
Manufacturer Name: Sigma-Aldrich
Quantity: 25
Unit of Measure: GR

Price: $156.79

List Price: $174.21

Application ( S )-BINOL ligand in combination with titanium(IV) isopropoxide, forms ( S )-(-)-BINOL-Ti complex, which is an effective chiral catalyst for: asymmetric addition of alkynylzinc to unactivated ketones enantioselective ring-opening

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Description
Specifications

Application

(S)-BINOL ligand in combination with titanium(IV) isopropoxide, forms (S)-(-)-BINOL-Ti complex, which is an effective chiral catalyst for:

asymmetric addition of alkynylzinc to unactivated ketones
enantioselective ring-opening reaction of meso-stilbene oxide and cyclohexene oxide with anilines
asymmetric aryl transfers from triaryl(tetrahydrofuran)aluminum reagents to a wide variety of ketones

It can also react with zirconium(IV) isopropoxide isopropanol complex to form a chiral Lewis acid catalyst for the facile enantioselective allylation of aldehydes by allyltributyltin.

Precursor to phosphoramidite catalyst employed in a conversion of allylic alcohols to allylic amines.

UPC:: 12352204
Condition:: New
Weight:: 1.00 Ounces
HazmatClass:: No
WeightUOM:: LB
MPN:: 246956-25G

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