General description
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a metal-salen complex that can catalyze a variety of asymmetric transformations.
Application
Reactant involved in:
- Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activity
- Immobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate)
- Synthesis of derivatvies for studies of conformational models of enantioselective reactions
Catalyst involved in:
- Asymmetric epoxidation of olefins
- Immobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcoholsâ€
- Immobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styrene
Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins. High enantioselectivities and yields are obtained for a variety of substrates, especially cis-alkenes. A few applications include the synthesis of the taxol side chain and cis-1-amino-2-indanol. Jacobsen′s catalyst has also been used in the asymmetric α-hydroxylation of silyl enol ethers. Catalyst for the enantioselective epoxidation of a variety of olefins.
Legal Information
Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.
- UPC:
- 51473001
- Condition:
- New
- Weight:
- 1.00 Ounces
- HazmatClass:
- No
- WeightUOM:
- LB
- MPN:
- 404454-25G