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(S)-T-BINAP

Catalog No.
C15-1198-448
Manufacturer No.
693030-500MG
Manufacturer Name
Sigma-Aldrich
Quantity
500
Unit of Measure
MG
Price: $164.10
List Price: $182.34

Application Takasago Ligands and Complexes for Asymmetric Reactions ( S )-T-BINAP reacts with silver nitrate to form ( S )-Tol-BINAP·AgNO 3 , which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary

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Application

Takasago Ligands and Complexes for Asymmetric Reactions

(S)-T-BINAP reacts with silver nitrate to form (S)-Tol-BINAP·AgNO3, which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary alcohols. It may be used as a chiral ligand in the palladium catalyzed asymmetric double carbohydroamination of iodoarenes to form α-aminoamides. It can also catalyze the asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate to form chiral N-allyl ortho-tert-butylanilides.

Legal Information

Sold in collaboration with Takasago for research purposes only.

UPC:
42143527
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
WeightUOM:
LB
MPN:
693030-500MG


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