1-Ethylpiperidine hypophosphite (C09-0881-478)

Description1-Ethylpiperidine hypophosphite promotes the carbon-carbon bond forming radical reactions in both aqueous and organic media. EPHP plays an important role of a good chain carrier during the radical addition ofgem-dihalocompounds to electron-deficient olefins. It has been reported as a suitable radical reducing agent for organic halides.Reagent for:Synthesis of spiroketals via intramolecular iodoetherificationA facile radical cyclization diverted to a rearrangement-cyclization with baseRadical deoxygenationSynthesis of allylic H-phosphinates1-Ethylpiperidine hypophosphite (EPHP) may be used in the following studies:As water-soluble chain carrier for the efficient radical cyclization in water for various hydrophobic substrates.In the main radical-cyclisation step for the synthesis of the phytotoxic metabolite alboatrin and its epimer.Preparation of bifunctional pentafluorophenyl/2,4,6-trichlorophenyl sulfonates.Chemoselective radical reduction of the iodine atom in 1-deoxy-1-halo-1-iodo-alditols. Specification: 0.95 MDL Number: MFCD00216621 Molecular Formula: C7H18NO2P Molecular Weight: 179.2 PubChem CID: 11492035 Isomeric SMILES: CCN1CCCCC1.OPO Related Documents: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/E467121-SCI_e0622c64b87ad60b858bf5e7389521bf.pdf