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2-formylphenyl sulfofluoridate (c15-1318-382)

2-Formylphenyl sulfofluoridate (C15-1318-382)

Catalog No.
C15-1318-382
Manufacturer No.
ALD00422-1G
Manufacturer Name
Sigma-Aldrich
Quantity
1
Unit of Measure
GR
Price: $125.91
List Price: $139.90

2-Formylphenyl sulfofluoridate is an aryl fluorosulfate. It can be synthesized from the reaction between phenol and sulfuryl fluoride in the presence of triethylamine.

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General description

2-Formylphenyl sulfofluoridate is an aryl fluorosulfate. It can be synthesized from the reaction between phenol and sulfuryl fluoride in the presence of triethylamine. It undergoes Sonogashira coupling reaction with phenyl acetylene.

Application

The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperature and are not air sensitive.

Other Notes

Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates

Molecular Weight: 204.18. Empirical Formula: C7H5FO4S. description: Fp: >. 230°F. Quality Level: 100. form: liquid. refractive index: n20/D 1.5086. density: 1.4545 . g/mL . at 25 . °C. SMILES string: O: S(OC1: C(C: O)C: CC: C1)(F): O. InChI: 1S/C7H5FO4S/c8-13(10,11)12-7-4-2-1-3-6(7)5-9/h1-5H. InChI key: SUOCJDDQQKVIKZ-UHFFFAOYSA-N. Pictograms: GHS05. Signal Word: Danger. Hazard Statements: H314. Precautionary Statements: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405. Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B. Storage Class Code: 8A - Combustible, corrosive hazardous materials. WGK: WGK 3. Flash Point(F): No data available. Flash Point(C): No data available.
UPC:
51283923
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
WeightUOM:
LB
MPN:
ALD00422-1G


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