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5-bromopyridin-3-yl sulfurofluoridate (c15-1318-399)

5-Bromopyridin-3-yl sulfurofluoridate (C15-1318-399)

Sigma-Aldrich

Catalog No.
C15-1318-399
Manufacturer No.
ALD00580-500MG
Manufacturer Name
Sigma-Aldrich
Quantity
500
Unit of Measure
MG
Price: $44.23
List Price: $49.14

Application 5-Bromopyridin-3-yl sulfurofluoridate can be used in the Pd-catalyzed Suzuki-Miyuara cross-coupling reaction. The fluorosulfate functionality was shown by Sharpless and coworkers to have distinct reactivity in comparison to other

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Application

5-Bromopyridin-3-yl sulfurofluoridate can be used in the Pd-catalyzed Suzuki-Miyuara cross-coupling reaction. The fluorosulfate functionality was shown by Sharpless and coworkers to have distinct reactivity in comparison to other functional groups used in Suzuki-Miyuara reactions, such as bromides, chlorides and triflates. This inherent property provides a strong potential for selective Suzuki-Miyuara couplings for chemoselective reaction sequences.

Other Notes

Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates
Chemoselective Synthesis of Polysubstituted Pyridines from Heteroaryl Fluorosulfates

Molecular Weight: 256.05. Empirical Formula: C5H3BrFNO3S. Quality Level: 100. Assay: ≥. 95%. form: solid or liquid. storage temp.: 2-8°C. Pictograms: GHS05,GHS07. Signal Word: Danger. Hazard Statements: H302 - H314. Precautionary Statements: P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363. Hazard Classifications: Acute Tox. 4 Oral - Skin Corr. 1B. Storage Class Code: 8A - Combustible, corrosive hazardous materials. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.
UPC:
51283927
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
WeightUOM:
LB
MPN:
ALD00580-500MG


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