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Cesium pivalate (C15-1222-353)

Sigma-Aldrich

Catalog No.
C15-1222-353
Manufacturer No.
694037-25G
Manufacturer Name
Sigma-Aldrich
Quantity
25
Unit of Measure
GR
Price: $502.53
List Price: $558.37

Cesium pivalate is an organic base widely used in palladium-catalyzed cross-coupling and carbonylation reactions due to its solubility in organic solvents . Application Cesium pivalate can be used as a base to synthesize: Fluoren-9-one derivatives

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General description

Cesium pivalate is an organic base widely used in palladium-catalyzed cross-coupling and carbonylation reactions due to its solubility in organic solvents.

Application

Cesium pivalate can be used as a base to synthesize:

  • Fluoren-9-one derivatives by cyclocarbonylation of o-halobiaryls in the presence of palladium catalyst.
  • Fused heterocycles (dihydrobenzofurans and indolines) from o-bromo phenol and aniline precursors via Pd-catalyzed intramolecular coupling of two C(sp3)-H bonds.
  • Amides and esters derivatives containing a quaternary β-carbon atom by Pd-catalyzed C-H activation and amino/alkoxycarbonylation reaction.
It can also be used as a base in the palladium-catalyzed Mizoroki-Heck reaction.

UPC:
51285409
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
WeightUOM:
LB
MPN:
694037-25G


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