Organosilicon Reagents

1-(Trimethylsilyl)imidazole (TMSI) was used for derivatization of carbohydrates into trimethylsilyl ethers. It was also used to synthesize polysubstituted chiral spirotetrahydropyrans and as silylating reagent for the protection of hydroxyl groups

1-(Trimethylsilyl)propyne was used in the synthesis of highly substituted indenes via palladium-catalyzed carboannulation and indenones via a rhodium-catalyzed reaction with 2-bromophenylboronic acids.

1-(Trimethylsilyl)propyne was used in the synthesis of highly substituted indenes via palladium-catalyzed carboannulation and indenones via a rhodium-catalyzed reaction with 2-bromophenylboronic acids.

1-(Trimethylsilyl)propyne was used in the synthesis of highly substituted indenes via palladium-catalyzed carboannulation and indenones via a rhodium-catalyzed reaction with 2-bromophenylboronic acids.

1-(Trimethylsilyl)propyne was used in the synthesis of highly substituted indenes via palladium-catalyzed carboannulation and indenones via a rhodium-catalyzed reaction with 2-bromophenylboronic acids.

1-[3-(Trimethoxysilyl)propyl]urea.

1-[3-(Trimethoxysilyl)propyl]urea.

1-[3-(Trimethoxysilyl)propyl]urea.

1-Bromo-3-(trimethylsilyl)benzene.

1-Bromo-3-(trimethylsilyl)benzene.

1-Bromo-4-(trimethylsilyl)benzene.

1-Bromo-4-(trimethylsilyl)benzene.