Chloro(1-t-butylindenyl)palladium(II) dimer (C09-0816-114)

ApplicationThe following palladium dimer is a precatalyst scaffold for cross-coupling reactions originally reported by the Hazari research group. When used with an selected ligand, the precatalyst exhibits superior activity over a wide array of cross-coupling reactions and under a variety of conditions.Product classM-C, Homogeneous Catalysts, Hazari Catalyst, Indenyl LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Suzuki-Miyaura Coupling ReactionChemical propertiesChemical formulaC26H30Cl2Pd2Empirical formula[Pd(1-tBu-Ind)Cl]2Molecular weight626.27MetalPdTheoretical metal content34Metal purity99.95Applications & referencesSuzuki-Miyaura coupling reaction catalyzed by an in situ generated solution of [Pd(cinnamyl)Cl]2 and IPr and an in situ generated solution of our Pd-cat. and IPr.Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)Suzuki-Miyaura coupling reaction of 2-chloro-4,6-dimethoxyprimidine and benzofuran-2-boronic acid catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)Suzuki-Miyaura coupling reaction of 2-chloro-1H-benzimidazole and 3-thiophene boronic acid catalyzed by an in situ precatalyst generated from Umicore our Pd-cat. and SPhos.Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)Suzuki-Miyaura coupling reaction of 2-methoxy chlorobenzene and morpholine catalyzed by an in situ precatalyst generated from our Pd-cat. and RuPhos.Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)Suzuki-Miyaura coupling reaction of 3-acetylpyridine and 3-chloropyridine catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)Suzuki-Miyaura coupling reaction of 4-chloroanisole and potassium isopropyltrifluoroboronate catalyzed by an in situ precatalyst generated from our Pd-cat. and P(tBu)3.Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)Hiyama-Denmark Reactions of 4-(trifluoromethyl)chlorobenzene and 4-(methoxy)phenyl silanolate catalyzed by in situ precatalysts generated from our Pd-cat. and different ligands.Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330). Specification: 99.95% metals basis Molecular Formula: C₂₆H₃0Cl₂Pd₂ Molecular Weight: 626.26 PubChem CID: 155885086 Related Documents: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/C293980-SCI_3b479fdc395f70156787a280c5e7a84e.pdf