DICHLOROTRIPHENYLPHOSPHORANE 95% (C15-1225-965)

Sigma Aldrich

Catalog No.: C15-1225-965
Manufacturer No.: 378755-25G
Manufacturer Name: Sigma-Aldrich
Quantity: 25
Unit of Measure: GR

Price: $176.27

List Price: $195.86

Dichlorotriphenylphosphorane (Triphenylphosphine dichloride, PPh 3 Cl 2 ) is a phosphorous halide. Stability and reactivity of dichlorotriphenylphosphorane have been studied by solid state 31 P NMR spectroscopy.

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Description
Specifications

General description

Dichlorotriphenylphosphorane (Triphenylphosphine dichloride, PPh₃Cl₂) is a phosphorous halide.Stability and reactivity of dichlorotriphenylphosphorane have been studied by solid state ³¹P NMR spectroscopy. It participates in the conversion of carboxylic esters to acid halides and mechanism of this cleavage has been investigated. Modified method has been proposed in which dichlorotriphenylphosphorane participates in the synthesis of tertiary amides.

Application

Dichlorotriphenylphosphorane may be used in the synthesis of the following:

tertiary benzanilide derivatives
N-phosphodipeptides
dialkyl phosphorochloridites based on the reaction of trialkyl phosphites
naphthalene ring-based calix[3]amide, via reaction with 6-amino-2-naphthoic acid
C_2v-symmetrical cyclic tetramers of aromatic amides

UPC:: 51286001
Condition:: New
Weight:: 1.00 Ounces
HazmatClass:: No
WeightUOM:: LB
MPN:: 378755-25G

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