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diethyl malonate (c15-1201-592)

Diethyl malonate (C15-1201-592)

Catalog No.
C15-1201-592
Manufacturer No.
D97754-1KG
Manufacturer Name
Sigma-Aldrich
Quantity
1
Unit of Measure
KG
Price: $189.11
List Price: $210.12

Diethyl malonate is diethyl ester of malonic acid. It is widely used as a versatile building block for introducing the malonate functional group into molecules.

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General description

Diethyl malonate is diethyl ester of malonic acid. It is widely used as a versatile building block for introducing the malonate functional group into molecules. Acylation of diethyl malonate using magnesium chloride and triethylamine is reported. K2CO3-catalyzed 1,4-addition reaction of diethyl malonate with various substituted 1,2-allenic ketones yields polyfunctionalized β,γ-unsaturated enones.

Application

Diethyl malonate was used to investigate Knoevenagel condensation reactions in microreactor using zeolite catalysts obtained by grafting amino groups onto NaX and CsNaX zeolites. It may be used in the synthesis of diethyl benzylidenemalonate by base catalyzed Knoevenagel condensation with benzaldehyde. It may be used in the synthesis of α-aryl malonates.

Packaging

Packaged in glass bottles

Legal Information

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

UPC:
51373101
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
WeightUOM:
LB
MPN:
D97754-1KG


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