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DIISOBUTYLALUMINUM HYDRIDE 1.0M SOLUTION IN DICHLOROMETHANE (C005B-010746)

Catalog No.
C005B-010746
Mfr. No.
214973-1L
Mfr. Name
Sigma-Aldrich
Qty/UOM
1
UOM
LI
Price: $564.84
List Price: $627.60

Diisobutylaluminum hydride is a reducing agent for many functional groups commonly used in organic synthesis. Application Diisobutylaluminum hydride solution (1 M in dichloromethane) has been used in the conversion of esters into

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General description

Diisobutylaluminum hydride is a reducing agent for many functional groups commonly used in organic synthesis.

Application

Diisobutylaluminum hydride solution (1 M in dichloromethane) has been used in the conversion of esters into α-fluoro-α,β-unsaturated esters in the presence of fluorocarboalkoxy-substituted dialkyl phosphonate anions via Horner-Wadsworth-Emmons reaction. It can be used in the multi-step synthesis of (S)-2-methyl tetrahydropyridine-N-oxide, a key structural moiety of bio-active compounds like himbacine and solenopsin-A.

Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.

Shipping Information:

Hazmat Fee: $65.00 + applicable shipping charges are added after the order is placed.

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UPC:
51362405
Condition:
New
Availability:
3-5 Days
Weight:
1.00 Ounces
HazmatClass:
Yes
MPN:
214973-1L
CAS:
1191-15-7
Temperature Control Device:
Yes

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