Dimethylzinc solution (C09-0862-803)

General DescriptionDimethylzinc (Zn(CH 3 ) 2 ) is a methylating reagent used to prepare methylated organic compounds as well as organometallic compounds containing methyl groups . It is also utilized as a reagent to prepare amino alcohols, oximes, and hydrazones from arylamines, alkoxyamines, and dialkylhydrazines respectively, by radical addition reaction in the presence of air and THF.ApplicationDimethylzinc solution can be used as: A catalyst with nickel for the stereoselective C−2 alkenylation and dialkenylation of pyridine derivatives by alkynes to give monoalkenylation products. A reagent with aldehydes and 2-methoxyaniline for the synthesis of enantioselective alkyl and aralkyl secondary amines via one-pot three-component coupling reaction in the presence of zirconium tetraisopropoxide. A methylating reagent for methylation of fluoroalkylated pyruvates in the presence of copper/chiral diphosphine catalyst. Specification: 1.0 M in heptane Molecular Formula: C2H6Zn Molecular Weight: 95.46 PubChem CID: 11010 Isomeric SMILES: [CH3-].[CH3-].[Zn+2] Beilstein Registry Number: 3587195 Related Documents: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/D432886-SCI_d92e7193d694a9103812a8f563d8ba97.pdf