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ETHYL ACETOACETATE FOR SYNTHESIS (C15-1214-801)

Catalog No.
C15-1214-801
Mfr. No.
8096229025
Mfr. Name
Sigma-Aldrich
Qty/UOM
25
UOM
LI
Price: $1,978.02
List Price: $2,197.80

Application Ethyl acetoacetate can be used as a reactant to synthesize: 7-hydroxycoumarin derivatives via Pechmann condensation reaction with 1,3-dihydroxybenzene in the presence of acid catalysts. 2,6-disubstituted piperidine alkaloid,

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Application

Ethyl acetoacetate can be used as a reactant to synthesize:

  • 7-hydroxycoumarin derivatives via Pechmann condensation reaction with 1,3-dihydroxybenzene in the presence of acid catalysts.
  • 2,6-disubstituted piperidine alkaloid, (−)-pinidinone via stereoselective α-aminoallylation followed by Grubbs′ olefin cross-metathesis reaction.
  • Michael addition products via Michael addition reaction with chalcones and azachalcones in the presence of a base catalyst.
  • α, β-unsaturated carbonyl compounds via Knoevenagel condensation reaction with glyceraldehyde acetonide in the presence of a base catalyst.

It can be also utilized as a reactant in the transesterification and asymmetric hydrogenation reactions to produce valuable products.

Analysis Note

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.028 - 1.030
Identity (IR): passes test

UPC:
51341803
Condition:
New
Availability:
3-5 Days
Weight:
1.00 Ounces
HazmatClass:
No
MPN:
8096229025
CAS:
141-97-9

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