N-Boc-pyrrole (C15-1245-564)

Sigma-Aldrich

Catalog No.: C15-1245-564
Manufacturer No.: 425834-100ML
Manufacturer Name: Sigma-Aldrich
Quantity: 100
Unit of Measure: ML

Price: $401.33

List Price: $445.92

N -Boc-pyrrole is an N -protected pyrrole. It undergoes Dielsâ€“Alder reaction with enantiomerically pure allene-1,3-dicarboxylates to form endo -adducts with retention in configurations at two newly generated stereogenic centers.

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Description
Specifications

General description

N-Boc-pyrrole is an N-protected pyrrole. It undergoes Dielsâ€“Alder reaction with enantiomerically pure allene-1,3-dicarboxylates to form endo-adducts with retention in configurations at two newly generated stereogenic centers. It also undergoes cyclopropanation with methyl phenyldiazoacetate to form both monocyclopropane and dicyclopropane. Its Ir-catalyzed C-H borylation followed by cross coupling with 3-chlorothiophene to form biheterocycle has been reported.

Application

N-Boc-pyrrole was used in the synthesis of 1-(tert-butoxycarbonyl)-1H-pyrrol-2-ylboronic acid by treating with n-BuLi and subsequent reaction with trimethyl borate.
It may be used as starting material in the synthesis of the following:

tropane drivatives
N-boc-2-(4-methoxyphenyl)pyrrole
N-boc-pyrrol-2-ylboronic acid

UPC:: 51453205
Condition:: New
Weight:: 1.00 Ounces
HazmatClass:: No
WeightUOM:: LB
MPN:: 425834-100ML

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