Palladium(II) chloride (C09-1018-829)

DescriptionPalladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2reacts withN,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II). Palladium dichloride, acetate and acetylacetonate in the [bmim][BF4] or [bmim][PF6] (where[bmim]+= 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.Palladium(II) chloride (PdCl2) was used in the following studies:As catalyst for the carbonylation of organic tellurides by reaction with carbon monoxide.As a catalyst along with Cu(II) for the deamination of phenethylamines to phenyl substituted pyrroles.Together with PEG 300, promoted efficient Suzuki-coupling of aryl chlorides with aryl boronic acids.Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar. Specification: ≥99.9% MDL Number: MFCD00003558 Molecular Formula: Cl2Pd Molecular Weight: 177.33 EC Number: 231-115-6 PubChem CID: 24290 Isomeric SMILES: Cl[Pd]Cl Related Documents: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/P465772-SCI_5afa072d41d226b1405f316c3a7fb405.pdf