(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride (C09-1047-389)

Product Describtion:(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a metal-salen complex that can catalyze a variety of asymmetric transformations.Product Application:Reactant involved in:Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activityImmobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate)Synthesis of derivatvies for studies of conformational models of enantioselective reactionsCatalyst involved in:Asymmetric epoxidation of olefinsImmobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcoholsImmobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styreneSalen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins. High enantioselectivities and yields are obtained for a variety of substrates, especially cis-alkenes. A few applications include the synthesis of the taxol side chain and cis-1-amino-2-indanol. Jacobsen′s catalyst has also been used in the asymmetric α-hydroxylation of silyl enol ethers.Catalyst for the enantioselective epoxidation of a variety of olefins. Specification: 0.98 Molecular Formula: [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]MnCl Molecular Weight: 635.2 PubChem CID: 135742506 Isomeric SMILES: CC(C)(C)C1=CC(=C(C(=C1)C(C)(C)C)O)C=N[C@H]2CCCC[C@@H]2N=CC3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)O.[Cl-].[Cl-].[Cl-].[Mn+3] Related Documents: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/S587065-SCI_70fa966b7bd4206473021be842309100.pdf