SnAP 3-Spiro-(2-Pyr) M Reagent (C15-1309-234)

General description

The product is a substituted SnAP [Sn(tin) amino protocol] reagent. SnAP reagents are air and moisture stable.

Application

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group

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Other Notes

Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles

Molecular Weight: 519.35. Empirical Formula: C₂₃H₄₈N₂O₃Sn. form: liquid. Quality Level: 100. refractive index: n/D 1.489. density: 1.122. storage temp.: −. 20°C. SMILES string: CCCC[Sn](CCCC)(COCC1(CN(C(OC(C)(C)C): O)CC1)N)CCCC. InChI: 1S/C11H21N2O3.3C4H9.Sn/c1-10(2,3)16-9(14)13-6-5-11(12,7-13)8-15-4. 3*1-3-4-2. /h4-8,12H2,1-3H3. 3*1,3-4H2,2H3. . InChI key: JLZWEXDNLRNRBE-UHFFFAOYSA-N. Pictograms: GHS06,GHS08,GHS09. Signal Word: Danger. Hazard Statements: H301 - H312 - H315 - H319 - H360FD - H372 - H410. Precautionary Statements: P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338. Hazard Classifications: Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1. Storage Class Code: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects. WGK: WGK 3.