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tbudavephos pd g3 (c15-1312-058)

tBuDavePhos Pd G3 (C15-1312-058)

Catalog No.
C15-1312-058
Manufacturer No.
903701-1G
Manufacturer Name
Sigma-Aldrich
Quantity
1
Unit of Measure
GR
Price: $354.49
List Price: $393.88

t BuDavePhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents.

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General description

tBuDavePhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has a long life in solutions. tBuDavePhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Application

tBuDavePhos Pd G3 has been used as a precatalyst for the Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids. It may also be used for a variety of C-C and C-N cross-coupling reactions.

Other Notes

Technology Spotlight: G3 and G4 Buchwald Precatalysts

Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids

Design and preparation of new palladium precatalysts for C-C and C-N cross-coupling reactions

linearFormula: C35H45N2O3PPdS · C4H8O. form: powder or crystals. feature: generation 3. reaction suitability: core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings. functional group: phosphine. SMILES string: CN(C1: C(C2: C(P(C(C)(C)C)C(C)(C)C)C: CC: C2)C: CC: C1)C.NC3: C(C4: C([Pd]OS(C)(: O): O)C: CC: C4)C: CC: C3.C5COCC5. Storage Class Code: 11 - Combustible Solids. WGK: WGK 3. Flash Point(F): Not applicable. Flash Point(C): Not applicable.
UPC:
51145202
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
WeightUOM:
LB
MPN:
903701-1G


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