trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene (C15-1247-354)

Sigma-Aldrich

Catalog No.: C15-1247-354
Manufacturer No.: 212830-5G
Manufacturer Name: Sigma-Aldrich
Quantity: 5
Unit of Measure: GR

Price: $331.53

List Price: $368.37

trans -1-methoxy-3-trimethylsiloxy-1,3-butadiene is a funtionalized Diels-Alder diene . Mukaiyama-Michael-type addition/heterocyclization of trans -1-methoxy-3-trimethylsiloxy-1,3-butadiene (Danishefsky′s diene) with 1,2-diaza-1,3-butadiene

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Description
Specifications

General description

trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene is a funtionalized Diels-Alder diene. Mukaiyama-Michael-type addition/heterocyclization of trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene (Danishefsky′s diene) with 1,2-diaza-1,3-butadiene has been investigated. Asymmetric hetero-Diels-Alder cyclization of Danishefsky′s diene with benzaldehyde catalyzed by mesoporous inorganic/metalorganic hybrid materials has been reported.

Application

trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene was used:

in the synthesis of sulfone analogues of griseofulvin (sulfogriseofulvins), 4H-1-aminopyrroles and 4,5H-pyrazoles
as Diels-Alder diene for the synthesis of pyridones and pyranones
as reagent employed in the Mannich-Michael reaction for preparation of piperidinones and enaminones

UPC:: 51111626
Condition:: New
Weight:: 1.00 Ounces
HazmatClass:: No
WeightUOM:: LB
MPN:: 212830-5G

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