Tris(dibenzylideneacetone)dipalladium(0) (C15-1245-279)

General description

Tris(dibenzylideneacetone)dipalladium(0) (Pd₂(dba)₃) participates in the synthesis of azepane. Crystal structure of Pd₂(dba)₃ has been determined by three-dimensional X-ray data. Crystals of Pd₂(dba)₃ are reported to crystalize in triclinic system. It is widely used Pd(0) source in Pd-mediated transformations.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:

• Synthesis of nanosized palladium phosphides upon interaction with white phosphorous
• Preparation of palladium triphenylphosphine carbonyl cluster complexes
• Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions
• Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes

• Suzuki cross-coupling reactions
• PCN- and PCS-pincer palladium complex catalyzed tandem allylation

• Catalyst for Suzuki coupling of aryl chlorides (eq. 1)
• Catalyst for Heck coupling of aryl chlorides (eq. 2)
• Catalyst for arylation of ketones (eq. 3)
• Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4)
• Catalyst for fluorination of allylic chlorides (eq. 5)
• Catalyst for β-arylation of carboxylic esters (eq. 6)
• Catalyst for carbonylation of 1,1-dichloro-1-alkenes (eq. 7)
• Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides (eq. 8)

For small scale and high throughput uses, product is also available as ChemBeads (919772)