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Sigma-Aldrich

(TRIBUTYLPHOSPHORANYLIDENE)ACETONITRILE 97%

(Tributylphosphoranylidene)acetonitrile or cyanomethylenetrimethylphosphorane (Bu 3 P=CHCN) is a Wittig reagent employed in the transformation of the carbonyl compounds, including aldehydes, esters, and lactones into the corresponding unsaturated

Description

General description

(Tributylphosphoranylidene)acetonitrile or cyanomethylenetrimethylphosphorane (Bu3P=CHCN) is a Wittig reagent employed in the transformation of the carbonyl compounds, including aldehydes, esters, and lactones into the corresponding unsaturated nitriles.

Application

(Tributylphosphoranylidene)acetonitrile can be utilized as a reagent in the:

  • Stereoselective synthesis of skytanthine and other O- and N-containing heterocycles by Mitsunobu intramolecular cycloalkylation.
  • Wittig olefination of esters, lactones, N-Boc lactam, and cyclic imide to corresponding Wittig products.

Specifications
UPC:
13111000
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
Quantity:
1
Unit of Measurement:
GR
MPN:
761060-1G
CAS:
157141-27-0
Catalog No. C005B-020313
Price: $452.78
List Price: $503.09
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