Aladdin Scientific
1,1′-Binaphthyl-2,2′-diamine (C007B-033659)
ApplicationNovel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1'-binaphthalenyl-2,2'-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective
Description
ApplicationNovel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1'-binaphthalenyl-2,2'-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective direct aldol reaction, organocatalyzed by recoverable BINAM- prolinamide derivatives can be highly accelerated by a catalytic amount of a carboxylic acid without a detrimental of the obtained enantioselectivities. Specification: 0.97 MDL Number: MFCD00145204 Molecular Formula: C20H16N2 Molecular Weight: 284.35 PubChem CID: 20571 Isomeric SMILES: C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)N)N Related Documents: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/B120051-SCI_7c5a481f3a5b686e02706c650da0b4bc.pdf
Specifications
- UPC:
- 51273300
- Condition:
- New
- Weight:
- 0.88 Ounces
- HazmatClass:
- Yes
- WeightUOM:
- LB
- MPN:
- B120051-1g
- CAS:
- 4488-22-6
- Health Hazards:
- Corrosive
- Product Size:
- 1g
- Hazard Statement Codes:
- H302:H318
- Precautionary Statement Codes:
- P264:P270:P280:P330:P301+P312:P305+P351+P338:P501
Catalog No.
C007B-033659
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