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Sigma-Aldrich

1 3-CYCLOHEXADIENE CONTAINS 0.05% BHT AS INHIBITOR 97% (C005B-050758)

Application 1,3-Cyclohexadiene can undergo: C-C coupling with aromatic alcohols via iridium-catalyzed hydrogen auto-transfer and with aldehydes via transfer hydrogenation mediated by isopropanol to form carbonyl addition products. Living anionic

Description

Application

1,3-Cyclohexadiene can undergo:

  • C-C coupling with aromatic alcohols via iridium-catalyzed hydrogen auto-transfer and with aldehydes via transfer hydrogenation mediated by isopropanol to form carbonyl addition products.
  • Living anionic polymerization with n-BuLi/TMEDA system to form polycyclohexadiene.
  • Platinum-catalyzed silaboration to form (1R,4S)-1-(dimethylphenylsilyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-cyclohexene.
  • Aerobic palladium-catalyzed 1,4-diacetoxylation in the presence of cobalt tetra(hydroquinone)porphyrin as an electron transfer reagent.

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Specifications
UPC:
51261601
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
Yes
Quantity:
5
Unit of Measurement:
ML
MPN:
C100005-5ML
CAS:
592-57-4
Catalog No. C005B-050758
Price: $162.48
List Price: $180.53
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