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Sigma-Aldrich

1 4-CYCLOHEXADIENE 97% (C005B-053965)

1,4-Cyclohexadiene is an effective hydrogen donor for catalytic hydrogenation reactions . It can rapidly replace benzyl groups of N -benzyloxycarbamates, benzyl esters, benzyl ethers and benzyl amines with hydrogen .

Description

General description

1,4-Cyclohexadiene is an effective hydrogen donor for catalytic hydrogenation reactions. It can rapidly replace benzyl groups of N-benzyloxycarbamates, benzyl esters, benzyl ethers and benzyl amines with hydrogen. It forms benzene at elevated temperatures in the presence of a ruthenium(II)-triphenylphosphine catalyst.

Application

1,4-Cyclohexadiene (1,4-CHD) was used to study the formation of parent ion from heavy fragmentation of 1,4-CHD on irradiation with a high-intensity laser pulse.

Useful for the reduction of radical intermediates formed in electron-transfer mediated ring-opening reactions

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Specifications
UPC:
12142207
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
Yes
Quantity:
25
Unit of Measurement:
ML
MPN:
125415-25ML
CAS:
628-41-1
Catalog No. C005B-053965
Price: $336.46
List Price: $373.84
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