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Sigma-Aldrich

1-BROMO-2-NITROBENZENE 98% (C005B-049884)

1-Bromo-2-nitrobenzene undergoes palladium[0]-mediated Ullmann cross-coupling reaction with a range of β-halo-enals, -enones or -esters to afford the corresponding β-aryl derivatives. Palladium[0]-mediated Ullmann cross-coupling reaction

Description

General description

1-Bromo-2-nitrobenzene undergoes palladium[0]-mediated Ullmann cross-coupling reaction with a range of β-halo-enals, -enones or -esters to afford the corresponding β-aryl derivatives. Palladium[0]-mediated Ullmann cross-coupling reaction of 1-bromo-2-nitrobenzene with β-bromo-α,β-unsaturated aldehydes is reported.

Application

1-Bromo-2-nitrobenzene may be used in the preparation of:

  • 4-methoxy-2′-nitrodiphenyl ether
  • 1-methoxy-3,5-bis-(2-nitro-phenoxy)benzene
  • 5-hydroxy-3-methoxy-2′-nitrodiphenyl ether

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Specifications
UPC:
51362102
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
Yes
Quantity:
100
Unit of Measurement:
GR
MPN:
365424-100G
CAS:
577-19-5
Catalog No. C005B-049884
Price: $943.04
List Price: $1,047.82
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