Allylpalladium(II) chloride dimer (C007B-000308)

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.Allylpalladium(II) chloride dimer has been employed for the following studies:● Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.● Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.● Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.● As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.ApplicationPrecatalysts for Asymmetric and Cross-Coupling CatalysisProduct classM-C, Homogeneous Catalysts, Allyl LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Allylic Alkylation, Buchwald-Hartwig Aminaton, Asymmetric Reactions, CH-Activation, Mizoroki Heck Coupling ReactionChemical propertiesChemical formulaC6H10Cl2Pd2Empirical formula[Pd(allyl)Cl]2Molecular weight365.89MetalPdTheoretical metal content58Physical statecrystallineColoryellow. Specification: Pd 58.2% MDL Number: MFCD00044874 Molecular Formula: C6H10Cl2Pd2 Molecular Weight: 365.89 EC Number: 234-579-8 PubChem CID: 61538 Isomeric SMILES: [CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+] Beilstein Registry Number: 4124623 Related Documents: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/A101182-SCI_f620b49c57c46f4e5a0d4a5ce25df5ed.pdf

UPC:

12190000

Condition:

New

Weight:

0.88 Ounces

HazmatClass:

No

Quantity:

1

Unit of Measurement:

EA

WeightUOM:

LB

MPN:

A101182-1g

CAS:

12012-95-2

Product Size:

1g

Hazard Statement Codes:

H302:H315:H317:H319:H335

Precautionary Statement Codes:

P261:P264:P270:P271:P272:P280:P330:P301+P312:P302+P352:P304+P340:P305+P351+P338:P333+P313:P362+P364:P405:P403+P233:P501