Allylpalladium(II) chloride dimer (C09-0712-654)

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.Allylpalladium(II) chloride dimer has been employed for the following studies:● Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.● Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.● Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.● As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.ApplicationPrecatalysts for Asymmetric and Cross-Coupling CatalysisProduct classM-C, Homogeneous Catalysts, Allyl LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Allylic Alkylation, Buchwald-Hartwig Aminaton, Asymmetric Reactions, CH-Activation, Mizoroki Heck Coupling ReactionChemical propertiesChemical formulaC6H10Cl2Pd2Empirical formula[Pd(allyl)Cl]2Molecular weight365.89MetalPdTheoretical metal content58Physical statecrystallineColoryellow. Specifications and Purity: Pd 58.2%. MDL Number: MFCD00044874. Molecular Formula: C6H10Cl2Pd2. Molecular Weight: 365.89. EC Number: 234-579-8. PubChem CID: 61538. Isomeric SMILES: [CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+]. Beilstein Registry Number: 4124623. Related Document: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/A101182-SCI_f620b49c57c46f4e5a0d4a5ce25df5ed.pdf