Allylpalladium(II) chloride dimer (C007B-016622)

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.Allylpalladium(II) chloride dimer has been employed for the following studies:● Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.● Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.● Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.● As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.ApplicationPrecatalysts for Asymmetric and Cross-Coupling CatalysisProduct classM-C, Homogeneous Catalysts, Allyl LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Allylic Alkylation, Buchwald-Hartwig Aminaton, Asymmetric Reactions, CH-Activation, Mizoroki Heck Coupling ReactionChemical propertiesChemical formulaC6H10Cl2Pd2Empirical formula[Pd(allyl)Cl]2Molecular weight365.89MetalPdTheoretical metal content58Physical statecrystallineColoryellowMetal purity99.95. Specification: 99.95% metals basis MDL Number: MFCD00044874 Molecular Formula: C6H10Cl2Pd2 Molecular Weight: 365.89 EC Number: 234-579-8 PubChem CID: 61538 Isomeric SMILES: [CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+] Beilstein Registry Number: 4124623 Related Documents: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/A284049-SCI_bfac67238486f022892525f5526c206b.pdf

UPC:

12190000

Condition:

New

Weight:

0.97 Ounces

HazmatClass:

No

Quantity:

1

Unit of Measurement:

EA

WeightUOM:

LB

MPN:

A284049-250mg

CAS:

12012-95-2

Product Size:

250mg

Hazard Statement Codes:

H315

Precautionary Statement Codes:

P264:P280:P302+P352:P332+P313:P362+P364