Dimethylzinc solution (C008B-273265)

Dimethylzinc can be used as: A catalyst with nickel for the stereoselective C−2 alkenylation and dialkenylation of pyridine derivatives by alkynes to give monoalkenylation products. A reagent with aldehydes and 2-methoxyaniline for the enantioselective synthesis of alkyl and aralkyl secondary amines via one-pot three-component coupling reaction in the presence of zirconium tetraisopropoxide. A methylating reagent for the methylation of fluoroalkylated pyruvates in the presence of a copper/chiral diphosphine catalyst. An activator for radical trifluoromethylation of silyl enol ethers leading to α-trifluoromethyl ketones.

Specifications & Purity: Dimethylzinc can be used as: A catalyst with nickel for the stereoselective C−2 alkenylation and dialkenylation of pyridine derivatives by alkynes to give monoalkenylation products. A reagent with aldehydes and 2-methoxyaniline for the enantioselective synthesis of alkyl and aralkyl secondary amines via one-pot three-component coupling reaction in the presence of zirconium tetraisopropoxide. A methylating reagent for the methylation of fluoroalkylated pyruvates in the presence of a copper/chiral diphosphine catalyst. An activator for radical trifluoromethylation of silyl enol ethers leading to α-trifluoromethyl ketones.

Molecular Formula: C2H6Zn

Molecular Weight: 95.46

EC Number: 208-884-1

PubChem CID: 11010

Isomeric SMILES: [CH3-].[CH3-].[Zn+2]

Beilstein: 3587195

Storage Temperature: Store at 2-8°C;Argon charged

Shipped in: Wet ice

More Information: https://ald-pub-files.oss-cn-shanghai.aliyuncs.com/aladdinsci/pdp/sds/1/D432887-SCI_97b97f871d7f0f7bbff4fe2825658adc.pdf

UPC:

41116105

Weight:

1.41 Ounces

HazmatClass:

Yes

Quantity:

1

Unit of Measurement:

EA

WeightUOM:

LB

MPN:

D432887-10ml

Country of Origin:

China

CAS:

544-97-8

Product Size:

10ml

Harmonized Tariff Code:

2931.90.90

Health Hazards:

Corrosive

Physical Hazards:

Flammable Liquid

Hazard Statement Codes:

H225;H250;H260;H304;H314;H336;H361d;H373;H411

Precautionary Statement Codes:

P210;P222;P223;P231;P233;P240;P241;P242;P243;P260;P264;P273;P280;P231+P232;P321;P363;P391;P301+P330+P331;P302+P335+P334;P303+P361+P353;P304+P340;P370+P378;P405;P402+P404;P403+P235;P501;P264+P265;P305+P354+P338;P317;P302+P361+P354;P316