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Sigma-Aldrich

PBDB-T-2CL

Application High-Efficiency Organic Solar Cells (OPVs) Polymeric donor material LUMO=𕒷.57 eV HOMO=𕒹.

Description

Application

High-Efficiency Organic Solar Cells (OPVs)
Polymeric donor material
LUMO=−3.57 eV
HOMO=−5.32 eV

OPV Device Performance :
PBDB-T-2Cl:IT-4F
Voc= 0.86V
Jsc= 21.46 mA/cm2
FF= 0.75
PCE=13.9%

PBDB-T-2Cl (or PM7) is a wide bandgap polymer donor (n-type semiconductor) containing chlorinated thienyl benzodithiophene (BDT-2Cl) used in high performance polymer solar cells (PSCs). PBDB-T-2Cl-based devices exhibit higher open circuit voltage (Voc) than the PBDB-T-2F-based devices, due to lower molecular energy levels of PBDB-T-2Cl, and leading to an outstanding power conversion efficiency of over 14%.
In general, chlorination is more effective than fluorination in downshifting the molecular energy levels and broadening the absorption spectra.

Specifications
UPC:
12142207
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
MPN:
906352-100MG
CAS:
2239295-71-5
Catalog No. C005B-026045
Price: $918.71
List Price: $1,020.79
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