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Sigma-Aldrich

TRIRUTHENIUM DODECACARBONYL 99% (C005B-019679)

Atomic number of base material: 44 Ruthenium Application Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates.

Description

General description

Atomic number of base material: 44 Ruthenium

Application

Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.

Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,Ÿ-unsaturated ketones providing good yields of α-pyrones.

Other Notes

A Practical Procedure for Reduction of Primary, Secondary and Tertiary Amides to Amines

Specifications
UPC:
51372600
Condition:
New
Weight:
1.00 Ounces
HazmatClass:
No
Quantity:
1
Unit of Measurement:
GR
MPN:
245011-1G
CAS:
15243-33-1
Controlled Substances and Cyanide:
Yes
Catalog No. C005B-019679
Price: $272.46
List Price: $302.74
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