Sigma-Aldrich
TRIRUTHENIUM DODECACARBONYL 99% (C005B-019679)
Atomic number of base material: 44 Ruthenium Application Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates.
General description
Atomic number of base material: 44 Ruthenium
Application
Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.
Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,Ÿ-unsaturated ketones providing good yields of α-pyrones.
Other Notes
A Practical Procedure for Reduction of Primary, Secondary and Tertiary Amides to Amines
- UPC:
- 51372600
- Condition:
- New
- Weight:
- 1.00 Ounces
- HazmatClass:
- No
- Quantity:
- 1
- Unit of Measurement:
- GR
- MPN:
- 245011-1G
- CAS:
- 15243-33-1
- Controlled Substances and Cyanide:
- Yes



